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Tech
 Notes
 技術專文
 Influence of Clean-   Figure 1.  Critical defect trend of EUV mask  Figure 2.  Defects image on EUV mask





 room Ambient Humidity   35             EUV masks defects-ITRS                                      5.00
                     30
                                        EUV mask inspection (Suppliers)
                     25
                                                                                                    4.00
 on the Formation of   Defect size [nm]  20                                                         2.00

                     15
                     10
 Nanoparticles        5 0


                       30
                                   20
                                    Flash Half Pitch [nm] 10  0     0        2.00      4.00      6.00  0  μm
 文│郭啟文│廠務技術發展專案│


 ೌྡྷ܃ᐑྤ᐀ܓ࿁׵
                 Introduction                   specified limits. The level to   With the application of an AFM
 քϷ୐ɿϮݑ͛ϓٙᅂᚤ                                    which these contaminations need   image survey, these defects show
                                                                               a random distribution with a
                                                to be removed depends upon
                 The prevailing cleanroom standard   the manufacture exquisite level   localized high density particle
 Water condensationed on wafer surfaces is highly related to the formation of nanometer size defect. In the   is the Federal Standard 209E which   required. There are many ways   region, ty pica l ly 5-25nm in
 manufacturing processes for semiconductor, a steady low-humidity environment is required. Furthermore, fi ndings   is a document that establishes   to control contamination of the   height and less than 500nm in
 from the history log of time versus defect numbers in the life span of silicon wafer storage show that means of   standard classes of air cleanliness   production, ambient humidity,   plane diameter, and these defects
 reducing wafer environment moisture could prevent defect formation and enhance yield greatly. This paper will study   for airborne particulate levels in   pressure, temperature, particle   could  easily be removed by water
 the relationship between humidity and nanoparticle defects in semiconductor manufacturing factories and a practical,   cleanrooms and clean zones, but   filtration, chemical filtration and   rinsing or heat treatment. It
 effective solution is proposed for this problem.  there is  more and more evidence   air flow directions  all need to be   appears that the time dependent
                 showing nanoparticles will be   tightly restricted.           ha ze may be approx i mately
                 the issue presenting an enormous                              close to the water spot. The
                 challenge to N10 and N7 production   Si l icon wa fe r s  a r e us e d  to   water adsorption on the wafer
                 in the semiconductor industry.   transfer patterns on the surface   surface is due to the existence of
                 Particle defects which have a  size   of the wafers. The fabrication of   ambient moisture which is very
                 of less than 20nm were usually   semiconductor circuits requires   adhesive to the airborne molecular
                 detected on the EUV mask[1]. The   multiple pattern layers, thus   contaminations. This is the main
                 trend chart and the AFM image   anything that is not intended   speculation to the flat dish shape
                 of particle defect on the EUV   to be deposited on the wafer   and high hydrosoluble properties
                 mask are shown in Figure 1 and   surface is regarded as defect. For   of the defects. Larry W. Shive et al.
                 Figure 2. Besides, nanoparticles are   example, the “time-dependent   performed a series of wafer storage
                 atomic force dominated defects   haze” (TDH). TDH is a formation   contamination studies. Dummy
                 which are difficult to remove,   of light point defects which  were   wafers were immediately packaged
                 different to the microparticle   not present when the bare wafers   for 6 and 18 months after thorough
                                                                                                      [2]
                 forces. With i n a cont rol led   just left the production line in the   clean and defect inspection . The
                 environment, the concentration of   manufacturing factory. The “time-  trend chart of the wafer defect size
                 airborne molecular contamination   dependent haze” is shown in Figure   larger than 0.12um after 6 month
                 and particles are controlled to   3.                          and 18 month storage is shown in





                                                                                       進入台積兩年餘,學習奈米粒子
                                                                                    啟文
                                                                                       污染防治的相關知識,很感謝長
                                                                                       官與同仁一路來的支持與協助,
                                                                                       提供我成長與修習的機會。
                                                                                  郭 Chi-Wen Kuo


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